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dc.contributor.authorDriver, Tom G.
dc.date.accessioned2011-08-31T19:23:23Z
dc.date.available2011-08-31T19:23:23Z
dc.date.issued2010-09-07
dc.identifier.bibliographicCitationDriver, T. G. 2010. Recent advances in transition metal-catalyzed N-atom transfer reactions of azides. Organic and Biomolecular Chemistry, 8(17): 3831-3846. DOI: 10.1039/c005219cen
dc.identifier.issn7-0539
dc.identifier.otherDOI: 10.1039/c005219c
dc.identifier.urihttp://hdl.handle.net/10027/7901
dc.descriptionThe definitive version is available through Royal Society of Chemistry at DOI: 10.1039/c005219cen
dc.description.abstractTransition metal-catalyzed N-atom transfer reactions of azides provide efficient ways to construct new carbon–nitrogen and sulfur–nitrogen bonds. These reactions are inherently green: no additive besides catalyst is needed to form the nitrenoid reactive intermediate, and the by-product of the reaction is environmentally benign N2 gas. As such, azides can be useful precursors for transition metal-catalyzed N-atom transfer to sulfides, olefins and C–H bonds. These methods offer competitive selectivities and comparable substrate scope as alternative processes to generate metal nitrenoids.en
dc.description.sponsorshipThe National Institutes of Health NIGMS (R01GM084945), Petroleum Research Fund administered by the American Chemical Society (46850-G1), and the University of Illinois at Chicago are acknowledged for their generous support of our research program.en
dc.language.isoen_USen
dc.publisherRoyal Society of Chemistryen
dc.subjectnitrenoiden
dc.subjectTransition metal-catalyzed N-atom transfer reactionsen
dc.titleRecent advances in transition metal-catalyzed N-atom transfer reactions of azidesen
dc.typeArticleen


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