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dc.contributor.authorBu, Wei
dc.contributor.authorHou, Binyang
dc.contributor.authorMihaylov, Miroslav
dc.contributor.authorKuzmenko, Ivan
dc.contributor.authorLin, Binhua
dc.contributor.authorMeron, Mati
dc.contributor.authorSoderholm, L.
dc.contributor.authorLuo, Guangming
dc.contributor.authorSchlossman, Mark L.
dc.date.accessioned2012-08-07T02:45:19Z
dc.date.available2012-08-07T02:45:19Z
dc.date.issued2011-11-15
dc.identifier.bibliographicCitationBu, W., Hou, B. Y., Mihaylov, M., Kuzmenko, I., Lin, B. H., Meron, M., Soderholm, L., Luo, G. M., & Schlossman, M. L. 2011. X-ray fluorescence from a model liquid/liquid solvent extraction system. Journal of Applied Physics, 110(10). DOI: 10.1063/1.3661983en
dc.identifier.issn0021-8979
dc.identifier.otherDOI: 10.1063/1.3661983
dc.identifier.urihttp://hdl.handle.net/10027/8431
dc.description© 2011 American Institute of Physics. The following article appeared in Bu, W., Hou, B. Y., Mihaylov, M., Kuzmenko, I., Lin, B. H., Meron, M., Soderholm, L., Luo, G. M., & Schlossman, M. L. 2011. X-ray fluorescence from a model liquid/liquid solvent extraction system. Journal of Applied Physics, 110(10). and may be found at http://jap.aip.org/resource/1/japiau/v110/i10/p102214_s1. DOI: 10.1063/1.3661983en
dc.description.abstractX-ray fluorescence near total reflection (XFNTR) is measured from the liquid/liquid interface between dodecane and an ErCl3 aqueous solution by monitoring L shell Er emission lines. A custom sample cell is used to minimize absorption of the fluorescence x-rays that pass through dodecane on their way to the detector. The Er3+ concentration near the interface is related to the fluorescence intensity by a scale factor that is extracted by fitting the incident-angle dependent Er La emission line intensities for different ErCl3 bulk concentrations. As an application, we present the use of XFNTR to monitor the growth of interfacial crud in a model solvent extraction system consisting of an interface between a dodecane solution of bis(2-ethylhexyl) phosphate (HDEHP) and an ErCl3 aqueous solution. VC 2011 American Institute of Physics. [doi:10.1063/1.3661983]en
dc.description.sponsorshipThis work was supported by the U.S. DOE, OBES, Chemical Sciences, Geosciences, and Biosciences Division under Contract No. DE- AC02-06CH11357. M.L.S. acknowledges the Chemistry Division of the NSF for partial support of this work. ChemMatCARS (Sector 15) is supported by NSF Chemistry and DOE; the latter under the same contract.en
dc.language.isoen_USen
dc.publisherAmerican Institute of Physicsen
dc.titleX-ray fluorescence from a model liquid/liquid solvent extraction systemen
dc.typeArticleen


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