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Reactivity of Arynes for Arene Dearomatization
(American Chemical Society, 2018-07-02)
An unprecedented aryne-mediated dearomatization reaction is described. An aryne intermediate generated from arenesulfonyl ynamide-tethered tri- and tetraynes reacts with both the π-systems of a tethered alkene and the ...
Reactivity of Arynes toward Functionalized Alkenes: Intermolecu-lar Alder-Ene vs. Addition Reactions
(Royal Society of Chemistry, 2018-05-12)
The selectivity between two different manifolds of reactions of arynes reacting with functionalized alkenes is described. Arynes generated from bis-1,3-diynes react with various trisubstituted and 1,1-disubstituted alkenes ...
Reactivity of arynes toward functionalized alkenes: intermolecular Alder-ene vs. addition reactions
(Royal Society of Chemistry, 2018-06-15)
The selectivity between two different manifolds of reactions of arynes reacting with functionalized alkenes is described. Arynes generated from bis-1,3-diynes react with various trisubstituted and 1,1-disubstituted alkenes ...
Reactivity of Arynes for Arene Dearomatization
(American Chemical Society, 2018-07-02)
An unprecedented aryne-mediated dearomatization reaction is described. An aryne intermediate generated from arenesulfonyl ynamide-tethered tri- and tetraynes reacts with both the π-systems of a tethered alkene and the ...