Now showing items 1-3 of 3
Co-catalysis: Role of Organic Cations in Oxygen Evolution Reaction on Oxide Electrodes
(American Chemical Society, 2018-07-31)
Cocatalysis is a promising approach toward enhanced electrocatalytic activity. We report such synergic
Thermodynamic Hydricities of Biomimetic Organic Hydride Donors
(American Chemical Society, 2018-03-26)
Thermodynamic hydricities (Δ GH-) in acetonitrile and dimethyl sulfoxide have been calculated and experimentally measured for several metal-free hydride donors: NADH analogs (BNAH, CN-BNAH, Me-MNAH, HEH), methylene ...
Benzimidazoles as Metal-Free and Recyclable Hydrides for CO2 Reduction to Formate
(American Chemical Society, 2018-11-27)
We report a novel metal-free chemical reduction of CO2 by a recyclable benzimidazole-based organo-hydride, whose choice was guided by quantum chemical calculations. Notably, benzimidazole-based hydride donors rival the ...